Karl Fischer Reagent Selection Guide
Applicable Moisture Content:0.1% ~ 100%
Instrument ModelWKT-C Series
Principle:The titrant is precisely dosed through a burette, and the moisture content is calculated from the volume consumed
Features:Wide application range, simple operation, low reagent cost
Applicable Moisture Content:1ppm ~ 1%(<1%)
Instrument ModelWKT-A Series
Principle:Iodine is generated in situ by electrolysis, and the moisture content is calculated from the electrolysis charge
Features:Extremely high sensitivity, no titer calibration required, ideal for trace moisture
| Titer | Applicable Moisture Content | Sample Type | First choice: Saifurui SFR | Preferred imports: Honeywell / Merck | Selection Tag |
|---|---|---|---|---|---|
| ~0.5 mg/mL | 0.01% ~ 0.5% | Extremely low moisture: dry solids, pure solvents | KFR-15 (pyridine-free) | Hydranal Composite 1(34827) Aquastar CombiTitrant 1(1.88001) | volumetric |
| ~1 mg/mL | 0.01% ~ 1% | Low moisture: dry solids, organic solvents | KFR-1 (pyridine-free) | Hydranal Composite 1(34827) Aquastar CombiTitrant 1(1.88001) | volumetric |
| ~2 mg/mL | 0.1% ~ 5% | Medium moisture: chemicals, APIs | KFR-2 (pyridine-free) | Hydranal Composite 2(34806) Aquastar CombiTitrant 2(1.88002) | volumetric |
| ~3 mg/mL | 0.5% ~ 10% | Medium-to-high moisture: general chemicals | KFR-03(pyridine-free)Standard with instrument KFR-06 (methanol type) | Hydranal Composite 2(34806) Aquastar CombiTitrant 2(1.88002) | VICOMETER standard |
| ~5 mg/mL | 1% ~ 100% | High moisture: food, aqueous solutions, slurries | KFR-05 (pyridine-free) | Hydranal Composite 5(34805) Aquastar CombiTitrant 5(1.88005) | volumetric |
| ~3 mg/mL (with pyridine) | 0.5% ~ 10% | Traditional formula, high reactivity | KFR-08 (with pyridine) | — | With pyridine |
| ~5 mg/mL (with pyridine) | 1% ~ 100% | Traditional formula, high reactivity | KFR-09 (with pyridine) | — | With pyridine |
| ~5 mg/mL | Aldehyde and ketone samples | Compounds containing aldehyde/ketone groups (side reactions with methanol) | KFR-04 (pyridine-free, for aldehydes and ketones) | Hydranal Composite 5K(34816) Aquastar CombiTitrant 5 Keto(1.88006) | For aldehydes and ketones |
| Titrant | Titer | Matching Solvent | First choice: Saifurui SFR | Preferred imports: Honeywell / Merck | Selection Tag |
|---|---|---|---|---|---|
| Titrant 2 | ~2 mg/mL | General solvent | KFR-T1 / KFR-T2 (pyridine-free) | Hydranal Titrant 2(34811)+ Solvent(34800) Aquastar Titrant 2(1.88011)+ Solvent(1.88015) | volumetric |
| Titrant 3 | ~3 mg/mL | General solvent | KFR-T03 / KFR-T06 (pyridine-free) | Hydranal Titrant 2(34811)+ Solvent(34800) | volumetric |
| Titrant 5 | ~5 mg/mL | General solvent | KFR-T02 / KFR-T05 (pyridine-free) | Hydranal Titrant 5(34801)+ Solvent(34800) Aquastar Titrant 5(1.88010)+ Solvent(1.88015) | volumetric |
| Titrant 3/5 (with pyridine) | 3 / 5 mg/mL | General solvent | KFR-T08 / KFR-T09 (with pyridine) | — | With pyridine |
| Titrant 5 E | ~5 mg/mL | Solvent E (ethanol type) | — | Hydranal Titrant 5 E(34712)+ Solvent E (low-toxicity ethanol type) | Low toxicity recommended |
| — | — | Oil-specific solvent | KFR-T02A / KFR-T03A solvent | Hydranal Solvent Oil(34749)/ Solvent CM | Oil-specific |
| Reagent Type | First choice: Saifurui SFR | Preferred imports: Honeywell / Merck | Applicable Samples |
|---|---|---|---|
| Anolyte (general) | KFR-C02(pyridine-free, 1.5g/100ml)Standard with instrument KFR-C06 (pyridine-free, 1.5g/100ml) KFR-C03 (pyridine-free, 1.5g/100ml) | Hydranal Coulomat A(34807) Aquastar CombiCoulomat(1.09255) AQUAMICRON AX(604-07485)/ AXI(621-01755) | Organic solvents, inorganic substances, gases; suitable for most industries |
| Catholyte (general) | KFR-C06 Catholyte (5mL×10 vials/box) | Hydranal Coulomat CG(34840) AQUAMICRON CXU(602-07501) | For use with general anolyte |
| Anolyte (for aldehydes and ketones) | KFR-C04 (pyridine-free, 1.0g/100ml) KFR-C12 (alcohol-ether type, 1.0g/100ml) KFR-C18 (alcohol-free, chloroform-free, for aldehydes and ketones) | Hydranal Coulomat AK(34820) Aquastar Anolyte K(1.09255) AQUAMICRON AKX(605-07591) | Ketones, aldehydes, silicone oils, lower carboxylic acids |
| Catholyte (for aldehydes and ketones) | KFR-C04 Catholyte (5mL×10 vials/box) | Hydranal Coulomat CG-K(34821) Aquastar Catholyte K | For use with aldehyde/ketone anolyte |
| For lithium batteries/electrolytes | KFR-C07 (pyridine-free, 1.2g/100ml) KFR-C09 (with pyridine, 1.0g/100ml) KFR-C10 (for boron salts) KFR-C11 (for additives) KFR-C16 (diol type) | Hydranal Coulomat E(34808)/ ADG(34809) HYDRANAL NEXTGEN A-FA + C-FA | Lithium battery electrolytes, VC, FEC, lithium salts, additives |
| Universal anode/cathode type | KFR-C01 (with pyridine, 1.0g/100ml) KFR-C08 (pyridine-free, 1.2g/100ml, universal with/without diaphragm) | Hydranal Coulomat A(34807)+ CG(34840) (mixed anode/catholyte type) | General samples, replacing imported reagents |
| Reagent Type | First choice: Saifurui SFR | Preferred imports: Honeywell / Merck | Remarks |
|---|---|---|---|
| General electrolyte (single solution) | KFR-C03 (pyridine-free, 1.5g/100ml, chlorinated-hydrocarbon-free) KFR-C08 (pyridine-free, 1.2g/100ml, universal with/without diaphragm) KFR-C20 (pyridine-free, same as 34836, universal anode/cathode) | Hydranal Coulomat AG(34836) Aquastar CombiCoulomat Fritless(1.09257) AQUAMICRON FLS(632-07065) | One reagent is enough; no catholyte needed |
| For Karl Fischer ovens | KFR-C02Standard with instrument · suitable for Karl Fischer ovens KFR-C19 (carbonate/glycolamine type, extremely low volatility) | — | KFR-C02 general type is also suitable for Karl Fischer ovens; routine solid samples can directly use the standard reagent; KFR-C19 is the extremely-low-volatility type, ideal for scenarios with extremely strict drift requirements |
| Model | Type | Titer F | Package Size | Application Notes |
|---|---|---|---|---|
| KFR-15 | Pyridine-free | ≥0.5 mgH₂O/mL | 500mL / 1L | Low titer, for samples with extremely low moisture |
| KFR-1 | Pyridine-free | ≥1 mgH₂O/mL | 500mL / 1L | Low-moisture samples, dry solids, pure solvents |
| KFR-2 | Pyridine-free | ≥2 mgH₂O/mL | 500mL / 1L | Medium moisture, chemicals, APIs |
| KFR-03Standard with instrument | Pyridine-free | ≥3 mgH₂O/mL | 500mL / 1L | Medium-to-high moisture, general chemicals.VICOMETER WKT-C series factory standard, suitable for routine samples in most industries |
| KFR-05 | Pyridine-free | ≥5 mgH₂O/mL | 500mL / 1L | High moisture, food, aqueous solutions, slurries |
| KFR-06 | Methanol type | ≥3 mgH₂O/mL | 500mL / 1L | Methanol system, suitable for general samples |
| KFR-08 | With pyridine | ≥3 mgH₂O/mL | 500mL / 1L | Traditional pyridine-containing formula, high reactivity |
| KFR-09 | With pyridine | ≥5 mgH₂O/mL | 500mL / 1L | Traditional pyridine-containing formula, high-moisture samples |
| KFR-04 | Pyridine-free · for aldehydes and ketones | ≥5 mgH₂O/mL | 500mL / 1L | For aldehyde and ketone samples, avoiding acetalization reactions |
| KFR-10 | With pyridine · for aldehydes and ketones | ≥3 mgH₂O/mL | 500mL / 1L | With pyridine, for aldehydes and ketones |
| Model | Type | Titer F | Package Size | Application Notes |
|---|---|---|---|---|
| KFR-T1 | Pyridine-free | ≥1 mgH₂O/mL | A:500mL/1L B:500mL/1L | Low-moisture two-component |
| KFR-T2 | Pyridine-free | ≥2 mgH₂O/mL | A:500mL/1L B:500mL/1L | Medium-moisture two-component |
| KFR-T03 | Pyridine-free | ≥3 mgH₂O/mL | A:500mL/1L B:500mL/1L | Medium-to-high-moisture two-component |
| KFR-T06 | Pyridine-free | ≥3 mgH₂O/mL | A:500mL/1L B:500mL/1L | Medium-to-high-moisture two-component |
| KFR-T02 | Pyridine-free | ≥5 mgH₂O/mL | A:500mL/1L B:500mL/1L | High-moisture two-component |
| KFR-T05 | Pyridine-free | ≥5 mgH₂O/mL | A:500mL/1L B:500mL/1L | High-moisture two-component |
| KFR-T08 | With pyridine | ≥3 mgH₂O/mL | A:500mL/1L B:500mL/1L | Pyridine-containing two-component |
| KFR-T09 | With pyridine | ≥5 mgH₂O/mL | A:500mL/1L B:500mL/1L | Pyridine-containing two-component (high titer) |
| KFR-T04A/T04B | Pyridine-free · for aldehydes and ketones | 1~5 mgH₂O/mL | 500mL / 1L | Aldehyde/ketone-specific solvent + titrant combination |
| KFR-T02A / KFR-T03A | Pyridine-free · solvent | — | 500mL / 1L | Routine volumetric solvent, used with titrant |
| KFR-12 / KFR-13 | Solutions A and B | 3~5 mgH₂O/mL | A: 500mL/1L B: 500mL/1L | Solution A is an iodine-methanol solution (titrant); Solution B is a sulfur dioxide-methanol solution (solvent) |
| Model | Type | Nominal Moisture Content | Package Size | Electrolytic Cell/Application |
|---|---|---|---|---|
| KFR-C01 | With pyridine · universal anode/cathode | 1.0 gH₂O/100mL | 500mL / 250mL | Universal for diaphragm cells; requires water equilibration before first use |
| KFR-C02Standard with instrument | Pyridine-free · universal anode/cathode | 1.5 gH₂O/100mL | 500mL | Universal for diaphragm cells.VICOMETER WKT-A series factory standard, suitable for most industries and samples, and also for Karl Fischer ovens |
| KFR-C03 | Pyridine-free · chlorinated-hydrocarbon-free | 1.5 gH₂O/100mL | 500mL | Universal with/without diaphragm, eco-friendly and chlorine-free |
| KFR-C04 | Pyridine-free · for aldehydes and ketones | 1.0 gH₂O/100mL | Anolyte: 500mL Catholyte: 5mL×10 vials | Measures aldehydes and ketones with diaphragm; use with matching catholyte |
| KFR-C06 | Pyridine-free · with diaphragm | 1.5 gH₂O/100mL | Anolyte: 500mL Catholyte: 5mL×10 vials | Universal for diaphragm cells; use with matching catholyte |
| KFR-C07 | Pyridine-free · for lithium batteries | 1.2 gH₂O/100mL | 500mL | Testing of lithium battery additives and electrolytes; no water equilibration required |
| KFR-C08 | Pyridine-free · universal with/without diaphragm | 1.2 gH₂O/100mL | Anolyte: 500mL Catholyte: 5mL×10 vials | Replaces imported reagents; quickly reaches stable drift on first use |
| KFR-C09 | With pyridine · electrolyte-specific | 1.0 gH₂O/100mL | 500mL | Testing of electrolytes containing VC, FEC, lithium salts, etc.; fast reaction and long life |
| KFR-C10 | Pyridine-free · for boron salts | 1.0 gH₂O/100mL | 500mL | Testing of pure LiBOB, ODFB and other boron salts; universal anode/cathode with diaphragm |
| KFR-C11 | Pyridine-free · for additives | 1.0 gH₂O/100mL | 500mL | Testing of VC, FEC, DTD and other additives; universal anode/cathode with diaphragm |
| KFR-C12 | Alcohol-ether type | 1.0 gH₂O/100mL | 500mL | Minimal side reactions with aldehyde/ketone samples; suitable for VC/FEC/NMP/acetone, etc. |
| KFR-C16 | Diol · diaphragm-specific | — | 500mL | Lithium salts/FEC/VC-containing electrolytes; good solubility, no crystallization |
| KFR-C18 | Alcohol-free, chloroform-free · for aldehydes and ketones | 1.0 gH₂O/100mL | 500mL | VC/FEC/NMP/acetone/cyclohexanone/vinyl ethers; minimal side reactions |
| KFR-C19 | Carbonate/glycolamine · for Karl Fischer ovens | — | 500mL | For Karl Fischer ovens; extremely low volatility, stable drift, universal with/without diaphragm |
| KFR-C20 | Pyridine-free · universal anode/cathode | 1.5 gH₂O/100mL | 500mL | Replaces imported reagents (same as 34836); universal with/without diaphragm and for anolyte/catholyte |
| Model | Nominal Moisture Content Value | Package Size | Application |
|---|---|---|---|
| KFR-W01 | 0.1 mg/g(0.01%) | 5mL×10 vials | Coulometric accuracy verification |
| KFR-W02 | 1.0 mg/g(0.1%) | 5mL×10 vials | Coulometric accuracy verification |
| KFR-W03 | 10.0 mg/g(1.0%) | 5mL×10 vials | Volumetric titer calibration |
| Saifurui SFR (part number = model) | Titer / Type | Honeywell HYDRANAL (order no.) | Merck Aquastar (product no.) | Mitsubishi AQUAMICRON (part no.) | Sinopharm Hushi (part number = model) |
|---|---|---|---|---|---|
| KFR-15 | 0.5 / pyridine-free | Composite 1 Part No.: 34827 | CombiTitrant 1 No.: 1.88001 | SS-Z 1mg Part No.: 631-03495 | — |
| KFR-1 | 1 / pyridine-free | Composite 1 Part No.: 34827 | CombiTitrant 1 No.: 1.88001 | SS-Z 1mg Part No.: 631-03495 | KFR-1 Pyridine-Free |
| KFR-2 | 2 / pyridine-free | Composite 2 Part No.: 34806 | CombiTitrant 2 No.: 1.88002 | SS-Z 3mg Part No.: 634-03505 | KFR-2 Pyridine-Free |
| KFR-03Standard with instrument | 3 / pyridine-free | Composite 2 Part No.: 34806 | CombiTitrant 2 No.: 1.88002 | SS-Z 3mg Part No.: 634-03505 | KFR-3 Pyridine-Free |
| KFR-05 | 5 / pyridine-free | Composite 5 Part No.: 34805 | CombiTitrant 5 No.: 1.88005 | SS-Z 5mg Part No.: 631-03515 | KFR-5 Pyridine-Free |
| KFR-06 | 3 / methanol type | Composite 2 Part No.: 34806 | CombiTitrant 2 No.: 1.88002 | — | KFR-3 Methanol Type |
| KFR-08 | 3 / with pyridine | Composite 2 (with pyridine) | — | SS 3mg (with pyridine) Part No.: 601-07015 | KFR-8 With Pyridine |
| KFR-09 | 5 / with pyridine | Composite 5 (with pyridine) | — | SS 10mg (with pyridine) Part No.: 603-07215 | KFR-9 With Pyridine |
| KFR-04 | 5 / for aldehydes and ketones | Composite 5K Part No.: 34816 | CombiTitrant 5 Keto No.: 1.88006 | SS-Z 5mg + KTX Part No.: 631-03515 / 632-03545 | For aldehydes and ketones |
| Saifurui SFR (part number = model) | Titer / Type | Honeywell HYDRANAL (order no.) | Merck Aquastar (product no.) | Mitsubishi AQUAMICRON (part no.) |
|---|---|---|---|---|
| KFR-T1 | 1 / pyridine-free | — | Titrant 1 + Solvent | — |
| KFR-T2 | 2 / pyridine-free | Titrant 2 + Solvent Part No.: 34811 + 34800 | Titrant 2 + Solvent No.: 1.88011 + 1.88015 | SS-Z 3mg + GEX Part No.: 634-03505 + 608-07525 |
| KFR-T03 / T06 | 3 / pyridine-free | Titrant 2 + Solvent Part No.: 34811 + 34800 | Titrant 2 + Solvent No.: 1.88011 + 1.88015 | SS-Z 3mg + GEX Part No.: 634-03505 + 608-07525 |
| KFR-T02 / T05 | 5 / pyridine-free | Titrant 5 + Solvent Part No.: 34801 + 34800 | Titrant 5 + Solvent No.: 1.88010 + 1.88015 | SS-Z 5mg + GEX Part No.: 631-03515 + 608-07525 |
| KFR-T08 | 3 / with pyridine | — | — | — |
| KFR-T09 | 5 / with pyridine | — | — | — |
| KFR-T04A/T04B | Two-component for aldehydes and ketones | Titrant 5 + Solvent K Part No.: 34801 + 34738 | Titrant 5 + Solvent Keto No.: 1.88010 + 1.88007 | SS-Z 5mg + KTX Part No.: 631-03515 + 632-03545 |
| KFR-T02A / T03A | General solvent | Solvent / Solvent Oil Part No.: 34800 / 34749 | Solvent / Solvent Oil No.: 1.88015 / 1.88020 | GEX / OLX Part No.: 608-07525 / 635-03535 |
| Saifurui SFR (part number = model) | Type / Application | Honeywell HYDRANAL (order no.) | Merck Aquastar (product no.) | Mitsubishi AQUAMICRON (part no.) | Sinopharm Hushi (part number = model) |
|---|---|---|---|---|---|
| KFR-C01 | With pyridine · universal for diaphragm cells | Coulomat A + CG Part No.: 34807 + 34840 | CombiCoulomat frit No.: 1.09255 | AX + CXU Part No.: 604-07485 + 602-07501 | Pyridine-containing coulometric electrolyte |
| KFR-C02Standard with instrument KFR-C03 | Pyridine-free · universal with/without diaphragm | Coulomat A / AG Part No.: 34807 / 34836 | CombiCoulomat frit / Fritless No.: 1.09255 / 1.09257 | AXI / FLS Part No.: 621-01755 / 632-07065 | Pyridine-free coulometric electrolyte |
| KFR-C06 | Pyridine-free · universal for diaphragm cells | Coulomat A (anolyte) Part No.: 34807 Coulomat CG (catholyte) Part No.: 34840 | CombiCoulomat frit No.: 1.09255 | AX (anolyte) Part No.: 604-07485 CXU (catholyte) Part No.: 602-07501 | Pyridine-free anolyte/catholyte |
| KFR-C04 | Pyridine-free · for aldehydes and ketones | Coulomat AK + CG-K Part No.: 34820 + 34821 | CombiCoulomat frit (for aldehydes and ketones) No.: 1.09255 | AKX + CXU Part No.: 605-07591 + 602-07501 | Electrolyte for aldehydes and ketones |
| KFR-C08 | Pyridine-free · universal with/without diaphragm | Coulomat AG Part No.: 34836 | CombiCoulomat Fritless No.: 1.09257 | FLS Part No.: 632-07065 | Diaphragm-free electrolyte |
| KFR-C20 | Pyridine-Free · Universal for Anode & Cathode (Same as 34836) | Coulomat AG Part No.: 34836 | CombiCoulomat Fritless No.: 1.09257 | FLS Part No.: 632-07065 | Universal Electrolyte |
| KFR-C07 | For lithium batteries/electrolytes | Coulomat E / ADG Cat. No.: 34808 / 34809 | — | — | — |
| KFR-C09 | With pyridine · electrolyte-specific | NEXTGEN Coulomat A-FA | — | — | — |
| KFR-C12 | For Alcohols/Ethers · Aldehydes & Ketones | Coulomat AK Cat. No.: 34820 | CombiCoulomat frit No.: 1.09255 | AKX Cat. No.: 605-07591 | — |
| KFR-C18 | Alcohol-free, chloroform-free · for aldehydes and ketones | Coulomat AK Cat. No.: 34820 | — | — | — |
| KFR-C16 | Diols · Lithium Battery (With Diaphragm) | Coulomat ADG Cat. No.: 34809 | — | — | — |
| KFR-C19 | For Karl Fischer ovens | — | — | — | — |
| Saifurui SFR (part number = model) | Nominal Moisture Content Value | Honeywell HYDRANAL (order no.) | Merck Aquastar (product no.) | Mitsubishi AQUAMICRON (part no.) | Application |
|---|---|---|---|---|---|
| KFR-W01 | 0.1 mg/g(0.01%) | Water Std 0.1 Cat. No.: 34847 | Water Std 0.01% Article No.: 1.88050 | Water Std 0.1mg Cat. No.: 639-15101 | Coulometric Verification |
| KFR-W02 | 1.0 mg/g(0.1%) | Water Std 1.0 Cat. No.: 34828 | Water Std 0.1% Article No.: 1.88051 | Water Std 1mg Cat. No.: 601-07571 | Coulometric Verification |
| KFR-W03 | 10.0 mg/g(1.0%) | Water Std 10.0 Cat. No.: 34850 | Water Std 1.0% Article No.: 1.88052 | Water Std 10mg Cat. No.: 608-07581 | Volumetric Titer Standardization |
Tablets, capsules, APIs, excipients
Alcohols, esters, ethers, amines
Gasoline, diesel, lubricating oil, insulating oil
Oils & fats, milk powder, seasonings, alcoholic drinks
Acetone, formaldehyde, acetaldehyde, etc.
Electronic-grade solvents, photoresists
Electrolytes, cathode & anode materials
Natural gas, LPG, inert gases
Pellets, resins, films
| Brand | Series | Origin | Recommended Volumetric Models | Recommended Coulometric Models | Positioning |
|---|---|---|---|---|---|
| Tianjin Saifurui SFR | SFR / Saifurui | Tianjin, China | KFR-03Standard / KFR-02/05 (Pyridine-Free) KFR-08/09 (With Pyridine) KFR-04 (For Aldehydes & Ketones) KFR-T Series (Two-Component) | KFR-C02Standard / C03/C06/C08 KFR-C04 (Aldehydes & Ketones) KFR-C07/C09 (Lithium Batteries) KFR-C12/C18 (Aldehydes, Ketones, Alcohols & Ethers) KFR-C20 (Universal Import Substitute) | First Choice |
| Honeywell | HYDRANAL® | Germany | Composite 1/2/5/5K Cat. No.: 34827/34806/34805/34816 Titrant 2/5 + Solvent Cat. No.: 34811/34801 + 34800 | Coulomat A/AG/CG/AK Cat. No.: 34807/34836/34840/34820 NEXTGEN A-FA/C-FA | Preferred Import |
| Merck | Aquastar® | Germany | CombiTitrant 1/2/5/5K Article No.: 1.88001/1.88002/1.88005/1.88006 Titrant 2/5 + Solvent Article No.: 1.88011/1.88010 + 1.88015 | CombiCoulomat frit (With Diaphragm) No.: 1.09255 CombiCoulomat Fritless (Without Diaphragm) No.: 1.09257 | Preferred Import |
| Mitsubishi Chemical | AQUAMICRON® | Japan | SS-Z 1mg/3mg/5mg Cat. No.: 631-03495/634-03505/631-03515 GEX/OLX/KTX/SU Solvents Cat. No.: 608-07525/635-03535/632-03545/603-07335 | AX(604-07485)/AXI(621-01755) AS(601-07255)/AKX(605-07591) CXU(602-07501)/FLS(632-07065) | Premium Import |
| Sinopharm Hushi | Sinopharm | China | With/Without Pyridine Types For aldehydes and ketones | Electrolytes With/Without Pyridine | Domestic Option |
| Aladdin / Macklin | Aladdin / Macklin | China | Pyridine-Free Volumetric Reagents | — | Domestic Option |
| Water Standard Type | Nominal Moisture Content Value | Applicable Method | Application | First Choice: Saifurui | Preferred Import |
|---|---|---|---|---|---|
| Liquid Water Standard 0.01% | 0.1 mg/g | coulometric | Coulometric accuracy verification | KFR-W01 | Hydranal Water Std 0.1 Cat. No.: 34847 Aquastar Article No.: 1.88050 |
| Liquid Water Standard 0.1% | 1.0 mg/g | coulometric | Coulometric accuracy verification | KFR-W02 | Hydranal Water Std 1.0 Cat. No.: 34828 Aquastar Article No.: 1.88051 |
| Liquid Water Standard 1.0% | 10.0 mg/g | volumetric | Volumetric titer calibration | KFR-W03 | Hydranal Water Std 10.0 Cat. No.: 34850 Aquastar Article No.: 1.88052 |
| Solid Water Standard 1% | 1.0% | Volumetric / Karl Fischer Oven | Karl Fischer Oven Verification | — | Hydranal Water Std KF-Oven Cat. No.: 34748 Aquastar Article No.: 1.88054 |
| Issue/Scenario | Cause Analysis | Solutions |
|---|---|---|
| High results for aldehyde/ketone samples | Aldehydes/ketones undergo acetalization with methanol, generating water and causing positive bias | Use aldehyde/ketone-specific reagents: Saifurui KFR-04 / KFR-C04 / KFR-C12; imported Hydranal Composite 5K / Coulomat AK |
| Poor dissolution of oil samples | Oils have low solubility in methanol, forming two phases | Use oil-specific solvents: Saifurui KFR-T02A/T03A; imported Solvent Oil / OLX, or add chloroform as a co-solvent |
| Strong acid/base samples out of pH range | Optimal pH for Karl Fischer reaction is 5-7; outside this range the reaction slows or becomes incomplete | Add buffer to adjust pH, or dilute before measurement |
| Large endpoint drift in coulometric titration | Aged electrolyte, contaminated diaphragm, ambient moisture ingress | Replace the electrolyte; check seals; keep the environment dry (recommended humidity <60%) |
| Unstable volumetric titer | Reagent moisture absorption, improper storage, leaks in the burette system | Store reagents tightly sealed and avoid frequent opening; check burette joint seals; standardize regularly |
| Solid samples cannot be measured directly | Sample insoluble in reagent; water cannot be released | Use a Karl Fischer oven: heat the sample to release water, which is carried into the titration cell by a carrier gas.The standard KFR-C02 universal electrolyte is also suitable for Karl Fischer ovens; conventional solid samples can be used directly. For extremely low volatility requirements, choose Saifurui KFR-C19 oven-dedicated electrolyte |
| Abnormal results for lithium battery electrolytes | VC, FEC, lithium salts and other components react side-wise with methanol | Use Saifurui KFR-C07/C09/C10/C11 lithium battery electrolytes; NEXTGEN A-FA is the imported option |
| Reagent color darkens | Iodine has been oxidized and released; the reagent may have expired | Replace the reagent immediately; check storage conditions (protect from light, keep cool and sealed) |
| Step 1: Water Content | Step 2: Sample Type | Step 3: Cell Type | Step 4: First Choice Saifurui | Step 4: Preferred Import |
|---|---|---|---|---|
| > 0.1% volumetric WKT-C Series | General Samples | — | KFR-03Standard KFR-05 (High Water Content) KFR-T05 + T02A (Two-Component) | Composite 2(34806)/ Titrant 5(34801)+ Solvent(34800) |
| Aldehydes & Ketones | — | KFR-04 (One-Component) KFR-T04A + T04B (Two-Component) | Composite 5K(34816)/ Titrant 5(34801)+ Solvent K(34738) | |
| Oils | — | KFR-T05 + KFR-T02A Solvent | Titrant 5(34801)+ Solvent Oil(34749) | |
| < 0.1% coulometric WKT-A Series | General Samples | With Diaphragm | KFR-C02Standard KFR-C06 (Anolyte) + Catholyte | Coulomat A(34807)+ CG(34840) |
| General Samples | Without Diaphragm | KFR-C08 / KFR-C20 | Coulomat AG(34836) | |
| Solids/Plastics (Karl Fischer Oven) | With/Without Diaphragm | KFR-C02Standard · Suitable for Karl Fischer Oven KFR-C19 (For Extremely Low Volatility) | Coulomat A(34807) | |
| Aldehydes & Ketones | With Diaphragm | KFR-C04 (Anolyte) + KFR-C04 Catholyte | Coulomat AK(34820)+ CG-K(34821) | |
| Lithium Batteries/Electrolytes | With Diaphragm | KFR-C07 / KFR-C09 | NEXTGEN Coulomat A-FA + C-FA |
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