Rubber & Plastics

Solution for Determining the Moisture Content of POM (Polyoxymethylene) with a Halogen Moisture Analyzer

How to determine the moisture content of POM (polyoxymethylene) with a halogen moisture analyzer? This is a question of great concern to POM (polyoxymethylene) suppliers and their customers. This article provides a moisture determination solution for typical POM (polyoxymethylene) samples. You will learn the operating procedures and specifications of the VM-E01 rapid halogen moisture analyzer, as well as how to use a halogen moisture analyzer to determine the moisture content of POM (polyoxymethylene) samples.

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VM-E01 Halogen Moisture Analyzer(0.1mg/0.0001g)

VM-E01 Halogen Moisture Analyzer(0.1mg/0.0001g)

Background

Plastic part suppliers and their customers care about quality and fast production. Proper moisture in raw material ensures trouble-free compounding and molding, smooth surfaces, and ideal mechanical properties. The VicoMeter VM-E01 rapid halogen moisture analyzer is ideal for simple, accurate moisture measurement on the production floor.

Measuring moisture in plastics with a halogen moisture analyzer is a recognized ASTM method: D6980-12, "Standard Test Method for Determination of Moisture in Plastics by Loss in Weight".

A VicoMeter solution for typical POM (polyoxymethylene) samples: measuring their moisture with the VM-E01 rapid halogen moisture analyzer, including operating procedures.

Related Information

Before measuring POM samples with the VM-E01, you may also want to know:

Common Questions About POM and Plastics

WKT-A9 Karl Fischer Trace Moisture Analyzer Coulometric

WKT-A9 Karl Fischer Trace Moisture Analyzer Coulometric

Reference Value Determination

The POM reference moisture value was determined with the VicoMeter WKT-A9 Karl Fischer moisture analyzer and WKT-V2 Karl Fischer oven; released moisture is carried by dry nitrogen into the electrolytic cell.

Recommended Settings for Plastics Industry Samples

If you have no reference method for plastics samples on the VM-E01, VicoMeter recommends these settings from experimental experience:

  • Heating mode: Standard

  • Shutoff mode: Automatic (1 mg/140 s)

  • Sample size: 30 g

  • Resolution: High (0.1 mg/0.0001 g)

  • Warm-up: standby, 100°C; at standby temperature, preheat the empty pan for 1 minute, then tare.

Selecting the Drying Temperature

Same Sample Heated at Two Different Temperatures

Figure 1: Same Sample Heated at Different Temperatures

(Click image to enlarge)

Choose a drying temperature matching the Karl Fischer reference value. Melting or marked color change means the temperature is too high. Some samples inevitably discolor when heated (polyamide unavoidably turns brown).

Figure 1 compares samples after two heating runs. Left: correct temperature — no melting or discoloration. Right: the sample browned, so the temperature was too high.

Plastic Sample Handling

Measure samples promptly. Otherwise, fill the container completely (use a smaller one if needed) and seal it to minimize air and prevent moisture uptake during storage.

Operating Steps for POM (Polyoxymethylene) Samples

Place the VM-E01 in a suitable spot, warm up 30 min, level it (bubble centered), and perform weighing and temperature calibration. Then measure POM samples (installation, environment, warm-up, calibration: seePreparation Before Formal Measurement with a Halogen Moisture Analyzeras discussed in that article; click the link to learn more.).

Halogen Moisture Analyzer Measurement Step: Taring

Tare Sample Pan

1. Place the empty pan on the center holder, preheat 1 min at 130°C standby, press tare to zero.

Halogen Moisture Analyzer Measurement Step: Spreading the Sample

Add Sample

2. Quickly spread about 30 g of POM sample evenly on the pan; wait for a stable reading.

Halogen Moisture Analyzer Measurement Step: One-Touch Start

One-Touch Start

3. Press start; the POM moisture result appears within minutes.

Test Data

VM-E01 Halogen Moisture Analyzer(0.1mg/0.0001g)

VM-E01 Halogen Moisture Analyzer(0.1mg/0.0001g)

VM-E01 Settings Reference

  • Heating mode: Standard

  • Heating Temperature: 130°C

  • Shutoff mode: Automatic (1 mg/140 s)

  • Sample size: 30 g

  • Resolution: High (0.1 mg/0.0001 g)

  • Warm-up: standby, 100°C; at standby temperature, preheat the empty pan for 1 minute, then tare.

Sample Information

  • Sample Description: POM, beige, high strength, good corrosion resistance, thermal stability, oxidation resistance, low hygroscopicity.

  • Typical Maximum Allowable Moisture Content [%]: 0.2

  • Hygroscopicity (23°C/50% rH) [%]: 0.2


Moisture Chart for POM Samples Before and After Drying

Moisture Chart for POM Samples Before and After Drying

Chart Notes

  • Recommendation: measure 6 POM samples with different moisture contents (dry vs. moist).

  • Green line:Moisture content (average) measured with the WKT-A9 Karl Fischer moisture analyzer and WKT-V2 Karl Fischer oven.

  • Blue line:Moisture content (average) measured with the VM-E01 rapid halogen moisture analyzer.

  • Red line:Typical maximum allowable moisture for pellet processing; refer to the supplier's material-specific values.


Moisture Data for POM Samples Before and After Drying

Sample InformationPOM Moisture Content Before DryingPOM Moisture Content After Drying
Test MethodHalogen Moisture AnalyzerKarl Fischer Moisture AnalyzersHalogen Moisture AnalyzerKarl Fischer Moisture Analyzers
Moisture %MC0.2170.2220.0340.030
Std Dev Δ0.0010.0020.0010.003
Test Time [min]2030730

Sample-Specific Test Notes

Maximum allowable moisture for pellet processing must always follow supplier specifications. Values here are typical only and may not suit your material or process.

These drying parameters were obtained on common plastics and do not cover all grades or colors; optimizing them may be needed for best results on a specific material.

FAQ

Can the Loss-on-Drying Method Measure Plastics?

Yes. Measuring moisture in plastics with a halogen moisture analyzer is a recognized ASTM method: D6980-12, "Standard Test Method for Determination of Moisture in Plastics by Loss in Weight".

Can a Rapid Halogen Moisture Analyzer Replace the Oven Method for Plastics?

Yes — seeCan Rapid Halogen Moisture Analyzers Replace the Oven Method?).

Can the same method for unreinforced plastics be used on reinforced plastics?

Yes — reinforced plastics contain glass or other materials that do not affect moisture measurement.

Can colorless-resin parameters be applied to a colored resin?

Adjust drying temperature for heat absorption — e.g., black resin about 10°C lower than white.

How to measure moisture in plasticized plastics?

Take care: loss on drying counts volatilized plasticizer as moisture. Heat at a lower temperature where possible to prevent plasticizer loss.

Can I apply my Karl Fischer oven temperature to the VM-E01?

Not directly. As a rule of thumb, the VM-E01 drying temperature is about 30°C lower than the oven's.

Can a method developed for one supplier's polymer be used on the same polymer type from other suppliers?

It is a good reference, but should be adapted to the other suppliers' polymer compounds.

Dr. Wei's Classroom

Polyoxymethylene (POM), also known as acetal resin, polyoxymethylene, or polyacetal, is a thermoplastic crystalline polymer hailed as "super steel" or "steel-like plastic."

POM is a high-performance engineering plastic, known abroad as a "steel substitute" or "super steel." With metal-like hardness, strength, and rigidity, excellent self-lubrication over wide temperature and humidity ranges, good fatigue resistance, elasticity, and good chemical resistance, POM is replacing zinc, brass, aluminum, and steel parts at lower cost than many other engineering plastics. It is widely used in electronics and electrical, machinery, instrumentation, consumer goods, automotive, building materials, and agriculture, with strong growth in medical technology and sports equipment.

Widely used for sliding and rotating parts — gears, levers, pulleys, sprockets, and especially bearings; hot water valves, precision metering valves, conveyor links and rollers, flow meters, automotive interior/exterior handles, cranks and window mechanisms, oil pump seats and impellers, gas switch valves, electronic switch parts, fasteners, terminals, mirror covers, fan parts, heating plates, instrument knobs; audio/video tape bearings; pipes and agricultural irrigation systems, valves, nozzles, faucets, bathtub parts; switch keypads, buttons, tape reels; temperature control timers; power and garden tool parts; surfboard, sailboat, and sled parts; watch micro-gears, sports equipment frames, backpack buckles, fasteners, lighters, zippers, clasps; pacemakers, artificial heart valves, spinal implants, and prosthetics.

Used in chemical and pharmaceutical synthesis, including synthesis using anhydrous formaldehyde as a raw material.

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Related Knowledge

Halogen Moisture Analyzer Halogen Moisture Analyzer

The halogen moisture analyzer is also known as a rapid halogen moisture meter, halogen moisture measuring instrument, halogen moisture tester, halogen moisture gauge, moisture tester, moisture meter, water content meter, moisture check meter, and more.

Karl Fischer Moisture Analyzers Karl Fischer Moisture Analyzers

A Karl Fischer moisture analyzer is an instrument designed on the Karl Fischer method to measure moisture content in materials. It is also known as a Karl Fischer moisture meter, fully automatic Karl Fischer moisture titrator, intelligent Karl Fischer trace moisture analyzer, or Fischer-method moisture meter, and comes in two types: coulometric and volumetric (titrimetric).

Karl Fischer Oven Karl Fischer Oven

A Karl Fischer oven is a heating device used together with a Karl Fischer moisture analyzer. It is commonly used to extract moisture from samples and assist the Karl Fischer moisture analyzer in testing the moisture content of samples. The Karl Fischer oven is also called a KF oven, KF auxiliary heating device, Karl Fischer heating unit, Karl Fischer heating furnace, Karl Fischer drying oven, gas-phase moisture extractor, or Karl Fischer sample heating oven.

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