How to Determine the Moisture Content of POM (Polyoxymethylene) with a Halogen Moisture Analyzer
How to determine the moisture content of POM (polyoxymethylene) with a halogen moisture analyzer? This is a question of great concern to POM (polyoxymethylene) suppliers and their customers. This article provides a moisture determination solution for typical POM (polyoxymethylene) samples. You will learn how to use a halogen moisture analyzer to determine the moisture content of POM (polyoxymethylene) samples, as well as the operating procedures and specifications of the VM-E01 rapid halogen moisture analyzer.
Plastic part suppliers and their customers care about quality and fast production. Proper moisture in raw material ensures trouble-free compounding and molding, smooth surfaces, and ideal mechanical properties. The VicoMeter VM-E01 rapid halogen moisture analyzer is ideal for simple, accurate moisture measurement on the production floor.
Measuring moisture in plastics with a halogen moisture analyzer is a recognized ASTM method: D6980-12, "Standard Test Method for Determination of Moisture in Plastics by Loss in Weight".
A VicoMeter solution for typical POM (polyoxymethylene) samples: measuring their moisture with the VM-E01 rapid halogen moisture analyzer, including operating procedures.
Before measuring POM samples with the VM-E01, you may also want to know:
Can a halogen moisture analyzer replace the oven method? Yes — seeCan Rapid Halogen Moisture Analyzers Replace the Oven Method?as discussed in that article.
How to choose a fast, accurate model? See"Rapid Halogen Moisture Analyzer Selection Guide"as discussed in that article.
Where to learn more about halogen moisture analyzers? See"Basic Knowledge of Rapid Halogen Moisture Analyzers"、"Explanation of Halogen Moisture Analyzer Technical Specifications"、《Halogen Moisture Analyzer》and other articles.
Other questions about measuring plastics? See the FAQ in"FAQ: Measuring Plastics with a Halogen Moisture Analyzer"as discussed in that article.
The POM reference moisture value was determined with the VicoMeter WKT-A9 Karl Fischer moisture analyzer and WKT-V2 Karl Fischer oven; released moisture is carried by dry nitrogen into the electrolytic cell.
If you have no reference method for plastics samples on the VM-E01, VicoMeter recommends these settings from experimental experience:
Heating mode: Standard
Shutoff mode: Automatic (1 mg/140 s)
Sample size: 30 g
Resolution: High (0.1 mg/0.0001 g)
Warm-up: standby, 100°C; at standby temperature, preheat the empty pan for 1 minute, then tare.
Choose a drying temperature matching the Karl Fischer reference value. Melting or marked color change means the temperature is too high. Some samples inevitably discolor when heated (polyamide unavoidably turns brown).
Figure 1 compares samples after two heating runs. Left: correct temperature — no melting or discoloration. Right: the sample browned, so the temperature was too high.
Measure samples promptly. Otherwise, fill the container completely (use a smaller one if needed) and seal it to minimize air and prevent moisture uptake during storage.
Place the VM-E01 in a suitable spot, warm up 30 min, level it (bubble centered), and perform weighing and temperature calibration. Then measure POM samples (installation, environment, warm-up, calibration: seePreparation Before Formal Measurement with a Halogen Moisture Analyzeras discussed in that article; click the link to learn more.).

1. Place the empty pan on the center holder, preheat 1 min at 130°C standby, press tare to zero.

2. Quickly spread about 30 g of POM sample evenly on the pan; wait for a stable reading.

3. Press start; the POM moisture result appears within minutes.
Heating mode: Standard
Heating Temperature: 130°C
Shutoff mode: Automatic (1 mg/140 s)
Sample size: 30 g
Resolution: High (0.1 mg/0.0001 g)
Warm-up: standby, 100°C; at standby temperature, preheat the empty pan for 1 minute, then tare.
Sample Description: POM, beige, high strength, good corrosion resistance, thermal stability, oxidation resistance, low hygroscopicity.
Typical Maximum Allowable Moisture Content [%]: 0.2
Hygroscopicity (23°C/50% rH) [%]: 0.2

Chart Notes
Recommendation: measure 6 POM samples with different moisture contents (dry vs. moist).
Green line:Moisture content (average) measured with the WKT-A9 Karl Fischer moisture analyzer and WKT-V2 Karl Fischer oven.
Blue line:Moisture content (average) measured with the VM-E01 rapid halogen moisture analyzer.
Red line:Typical maximum allowable moisture for pellet processing; refer to the supplier's material-specific values.
| Sample Information | POM Moisture Content Before Drying | POM Moisture Content After Drying | ||
| Test Method | Halogen Moisture Analyzer | Karl Fischer Moisture Analyzers | Halogen Moisture Analyzer | Karl Fischer Moisture Analyzers |
| Moisture %MC | 0.217 | 0.222 | 0.034 | 0.030 |
| Std Dev Δ | 0.001 | 0.002 | 0.001 | 0.003 |
| Test Time [min] | 20 | 30 | 7 | 30 |
Sample-Specific Test Notes
Maximum allowable moisture for pellet processing must always follow supplier specifications. Values here are typical only and may not suit your material or process.
These drying parameters were obtained on common plastics and do not cover all grades or colors; optimizing them may be needed for best results on a specific material.
Yes. Measuring moisture in plastics with a halogen moisture analyzer is a recognized ASTM method: D6980-12, "Standard Test Method for Determination of Moisture in Plastics by Loss in Weight".
Yes — seeCan Rapid Halogen Moisture Analyzers Replace the Oven Method?).
Yes — reinforced plastics contain glass or other materials that do not affect moisture measurement.
Adjust drying temperature for heat absorption — e.g., black resin about 10°C lower than white.
Take care: loss on drying counts volatilized plasticizer as moisture. Heat at a lower temperature where possible to prevent plasticizer loss.
Not directly. As a rule of thumb, the VM-E01 drying temperature is about 30°C lower than the oven's.
It is a good reference, but should be adapted to the other suppliers' polymer compounds.
Polyoxymethylene (POM), also known as acetal resin, polyoxymethylene, or polyacetal, is a thermoplastic crystalline polymer hailed as "super steel" or "steel-like plastic."
POM is a high-performance engineering plastic, known abroad as a "steel substitute" or "super steel." With metal-like hardness, strength, and rigidity, excellent self-lubrication over wide temperature and humidity ranges, good fatigue resistance, elasticity, and good chemical resistance, POM is replacing zinc, brass, aluminum, and steel parts at lower cost than many other engineering plastics. It is widely used in electronics and electrical, machinery, instrumentation, consumer goods, automotive, building materials, and agriculture, with strong growth in medical technology and sports equipment.
Widely used for sliding and rotating parts — gears, levers, pulleys, sprockets, and especially bearings; hot water valves, precision metering valves, conveyor links and rollers, flow meters, automotive interior/exterior handles, cranks and window mechanisms, oil pump seats and impellers, gas switch valves, electronic switch parts, fasteners, terminals, mirror covers, fan parts, heating plates, instrument knobs; audio/video tape bearings; pipes and agricultural irrigation systems, valves, nozzles, faucets, bathtub parts; switch keypads, buttons, tape reels; temperature control timers; power and garden tool parts; surfboard, sailboat, and sled parts; watch micro-gears, sports equipment frames, backpack buckles, fasteners, lighters, zippers, clasps; pacemakers, artificial heart valves, spinal implants, and prosthetics.
Used in chemical and pharmaceutical synthesis, including synthesis using anhydrous formaldehyde as a raw material.
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